105
V-4. APPLICATION TO THE BALTIC SEA
In this particular application to the Baltic Sea, a constant and uniform suspended matter
concentration over the domain, 4.5 mg/l, has been considered. The model was calibrated using
the 137Cs inventories over the whole Baltic Sea in water and sediments estimated from
measurements. A standard value, determined for Cs from experiments [V-11] was used for k2
and the forward rate, k1, can be determined from k2 and the equilibrium distribution coe?cient,
kd, as explained in Refs. [V-6–9]:
?? =
?
??
?
??
(V-20)
Good results are obtained with kd = 3 m3/kg, which is close to the recommended value by the
International Atomic Energy Agency [V-12]: 4 m3/kg. In addition, the sediment mixing depth
(distance until which the dissolved phase interacts with the sediment) was set to 2 cm. Finally,
a correction factor which takes into account that part of the sediment particle surface may be
hidden by other sediment particles is introduced (? = 0.001). A detailed formulation of the
model may be seen [V-6–9]. In summary, three parameters are optimized, i.e. the equilibrium
distribution coe?cient, sediment mixing depth and sediment correction factor.
Once the temporal evolution of 137Cs inventories in the Baltic Sea in the water column and
sediments are adequately reproduced by the model, mean 137Cs concentrations in several
sub-basins were extracted from the model, without any extra tuning, and compared with field
data.