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Volltext : 38: Nordseezustand 2003

Sum  mary

18

Nordseezustand  2003

els  since  1975.  The  lindane  concentration  was  found  to  be  about  18  %  below  the  prioryear
  level.  Since  1998,  lindane  levels  have  decreased  by  over  90  %.
Out  of  the  group  of  unpolar  chlorinated  hydrocarbons  (CHC),  the  contaminant  classes
HCB,  PCB,  and  DDT  were  investigated.  All  of  the  three  groups  had  comparable  spatial
distribution  patterns  in  German  Bight  water,  with  elevated  levels  near  the  coasts.  Because ­
  of  the  high  variability  of  measured  values  and  the  relatively  short  observation
period,  no  temporal  trend  has  been  found  either  in  water  or  in  sediment.
In  the  North  Sea,  a  background  load  of  aliphatic  hydrocarbons  (residues  of  petroleum
hydrocarbons)  was  identified.  Slightly  elevated  concentrations  were  found  in  the  German ­
  Bight  and  in  the  area  of  production  platforms  off  the  coast  of  Scotland.  However,
natural  background  levels  of  aliphatic  hydrocarbons  from  biogenic  sources  are  dominant ­
  in  large  parts  of  the  North  Sea.
Polycyclic  aromatic  hydrocarbons  (PAH,  e.  g.  naphthalene,  anthracene,  benzo[a]pyrene)
  are  compounds  forming  in  combustion  processes;  they  are  also  present
in  petroleum  products.  Most  of  them  are  carcinogenic.  In  water,  they  showed  typical
concentration  gradients  from  the  coasts  to  the  open  sea,  depending  on  their  molecular
size.  Elevated  levels  of  naphthalene  were  found  not  only  in  the  sea  area  influenced  by
discharges  from  the  Elbe  river  but  also  off  the  Themse  estuary,  the  coast  of  Scotland,
and  the  Norwegian  coast.  Based  on  the  ratios  of  the  individual  PAHs  in  water,  it  was
possible  to  identify  and  explain  local  hot  spots.  The  highest  PAH  levels  in  sediment
were  found  in  the  Elbe  estuary  and  in  the  White  Bank  area,  which  is  comparable  to  the
CHC  pattern.
Of  the  37  polar  plant  protection  agents  investigated  (insecticides  and  herbicides),  21
substances  were  found  in  the  Elbe,  and  20  in  the  German  Bight.  Usually,  these  compounds ­
  show  a  marked  annual  cycle,  which  depends  on  the  seasonal  use  of  pesticides ­
  in  farming.  The  herbicides  atrazine  and  simazine  were  still  present  at  relatively
high  concentrations  (1  -4ng/L)  in  the  German  Bight  although  their  use  has  been
banned  in  Germany  for  several  years.  Also  relatively  high  levels  (1  -  7.5  ng/L)  of  the
herbicides  diurone  and  isoproturone  were  found.  TBT,  a  compound  used  in  ship  paints
which  has  hormone-disrupting  properties  even  at  extremely  low  concentrations,  still  is
of  high  ecological  relevance.  The  concentrations  of  1  -  2  ng/L  observed  in  coastal  water ­
  have  already  reached  the  toxic  threshold  level.

Metals
The  concentrations  of  some  metals  in  coastal  water,  and  locally  in  sediment,  were  still
far  above  the  natural  background  levels  in  some  areas.  Cadmium,  copper,  mercury,
lead,  and  zinc  in  the  dissolved  phase  showed  a  strong  concentration  gradient  from  the
coast  to  the  open  sea,  like  most  organic  contaminants.  The  highest  levels  were  measured ­
  in  the  area  of  the  Elbe  estuary  and  along  the  North  Frisian  coast.  Near  the  coast,
the  background  levels  of  all  of  the  above  elements  were  clearly  exceeded;  in  the  open
North  Sea,  only  the  copper  concentrations  were  elevated.  Compared  to  the  preceding
years,  however,  the  metal  concentrations  in  water  were  not  unusually  high.
The  highest  metal  concentrations  were  observed  in  fine-grained  surface  sediments
southeast  of  Helgoland  and  in  the  area  of  the  White  Bank,  where  fine-grained  sediments ­
  prevail.  Metal  concentrations  in  the  study  area  were  found  to  be  mostly  stagnant ­
  or  to  have  a  downward  trend.  In  2003,  following  the  1999  -  2002  phase  of  mark ­
            
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